One Single Molecule as a Multifunctional Fluorescent Probe for Ratiometric Sensing of Fe3+, Cr3+ and Colorimetric Sensing of Cu2+
نویسندگان
چکیده
The reagent Rh-C, incorporating a rhodamine moiety and a coumarin backbone and prepared via click chemistry, was developed as the first single molecule for detecting Cu2+, Fe3+ and Cr3+. Its response to Cu2+ in different solutions is visible to the naked eye and it exhibits a ratiometric fluorescence response to Fe3+ in methanol and Cr3+ in acetonitrile.
منابع مشابه
An amine/imine functionalized microporous MOF as a new fluorescent probe exhibiting selective sensing of Fe3+ and Al3+ over mixed metal ions
Nowadays metal-organic frameworks with multiple luminescent centers are very fascinating as multifunctional luminescent material because of their luminescence properties, which could be systematically tuned by deliberate use of organic ligands and metal ions. In this research, we explored a microporous mixed-ligand MOF for highly selective and sensitive detection of metal ions. A two-fold inter...
متن کاملA novel diethyl 2-(9-fluorenyl) malonate functionlized SBA-15 for selective optical sensing of Iron
In this study, highly ordered mesoporous silica material (SBA-15) functionalized with Diethyl 2 - (9 -fluorenyl) malonate as a flourophore is reported. The anchoring of flourophores to the hydroxyl group on SBA-15 surface was done with post synthesis method. The obtained materials were characterized by small and wide angle X-ray diffraction, N2 adsorption–desorption, Fourier transform infrared ...
متن کاملA water-soluble near-infrared probe for colorimetric and ratiometric sensing of SO2 derivatives in living cells.
A coumarin TCF-based water-soluble near-infrared fluorescent probe was presented, which could be used for the rapid, colorimetric and ratiometric detection of SO2 derivatives with a detection limit of 0.27 nM. Moreover, this probe could successfully image the analyte in living cells.
متن کاملColorimetric and fluorescent probes for real-time naked eye sensing of copper ion in solution and on paper substrate
In this paper, BT ((E)-2-(4-(4-(bis(pyridin-2-ylmethyl)amino)styryl)-3-cyano-5,5-dimethylfuran-2(5H)-ylidene)malononitrile) with strong donor-π-acceptor structure was synthesized, which showed both colorimetric and fluorescent sensing ability toward Cu2+ with high selectivity and sensitivity. Job plot and mass spectra measurement revealed a 1 : 1 coordination mode between Cu2+ and probe BT in e...
متن کاملEngineering a FRET strategy to achieve a ratiometric two-photon fluorescence response with a large emission shift and its application to fluorescence imaging.
Two-photon excitation (TPE) probe-based fluorescence imaging has become one of the most attractive diagnostic techniques to investigate biomolecules and biological events in live cells and tissues. At the current stage most of the TPE-based sensing is reflected by fluorescence intensity changes. Nevertheless the mere altering of intensity could be facilely affected by ambient conditions. On the...
متن کامل